Electrochemical Properties and Charge Storage Profiles of Polyaniline-Graphene Hydrogel Supercapacitor Electrodes

International Journal of Chemistry | Vol. 11, No. 4, April 2020 | pp. 25–32

DOI: 10.46882/2020/IJC/000138

Article Type: Original Research Paper

Title: Electrochemical Properties and Charge Storage Profiles of Polyaniline-Graphene Hydrogel Supercapacitor Electrodes

Names of Authors: U. B. Aliyu¹, K. Y. Lee²*

Authors’ Affiliations:
¹Department of Chemistry, Ahmadu Bello University, Zaria, Nigeria.
²Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore.

Abstract: Fabricating highly efficient electrochemical energy storage units requires the development of hybrid polymer electrodes that exhibit high specific capacitance and fast ion diffusion kinetics. This research details the synthesis and electrochemical characterization of polyaniline-graphene hydrogel (PANI-GH) self-assembling nanocomposites prepared via in situ chemical oxidative polymerization pathways. The surface topology and morphological features of the hybrid gels were analyzed using field emission scanning electron microscopy (FESEM), FT-IR, and Raman spectroscopy. FESEM imaging confirmed that a highly porous three-dimensional polyaniline layer was uniformly deposited across the conductive graphene skeletal network. Electrochemical performance was investigated via cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) loops in a 1.0 M H₂SO₄ electrolyte system. The optimized PANI-GH hybrid electrode delivered a maximum specific capacitance of 485 F/g at a current density of 1.0 A/g, which was substantially higher than standalone pure polyaniline films (215 F/g). Electrochemical impedance spectroscopy (EIS) data showed a very low charge-transfer resistance of 0.28 ohms, confirming accelerated ionic transport across the polymeric interface. Cyclic stability evaluations proved that the composite material retained 91.2% of its capacitive profile after 2000 continuous cycles.

Keywords: Polyaniline; Graphene hydrogel; Energy storage; Supercapacitors; Cyclic voltammetry; Specific capacitance

Manuscript Timeline: Received: July 22, 2019; Revised: August 25, 2019; Accepted: September 18, 2019; Published: April 02, 2020.

Citation: Aliyu, U. B., & Lee, K. Y. (2020). Electrochemical Properties and Charge Storage Profiles of Polyaniline-Graphene Hydrogel Supercapacitor Electrodes. International Journal of Chemistry, 11(4), 25–32.

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